a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)

Áp dụng quy tắc đường chéo:

\(a.\\ \Rightarrow\dfrac{V_{Cl_2}}{V_{O_2}}=\dfrac{15,6}{23,4}=\dfrac{2}{3}\\ \Rightarrow\left\{{}\begin{matrix}\%V_{Cl_2}=40\%\\\%V_{O_2}=60\%\end{matrix}\right.\)

\(b.\) 

Ta có: \(\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{2}{3}\Leftrightarrow\dfrac{m_{Cl_2}}{m_{O_2}}=\dfrac{71.2}{32.3}=\dfrac{71}{48}\Leftrightarrow48m_{Cl_2}-71m_{O_2}=0\)

Mặt khác: \(m_{Cl_2}+m_{O_2}=5,95\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Cl_2}=3,55\left(g\right)\\m_{O_2}=2,4\left(g\right)\end{matrix}\right.\)

Giả sử có 1 mol khí Cl₂, 2 mol khí O₂

a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)

b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)

=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)

c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

=> m_A = 0,3.45 = 13,5 (g)

Đặt x và y là số mol O 3  và  O 2  có trong 1 mol hỗn hợp khí

Hỗn hợp khí A : (48x + 32y)/(x+y) = 19,2 x 2 = 38,4

→ 3x = 2y → 40% O 3  và 60%  O 2

Đặt x và y là số mol  H 2  và CO có trong 1 mol hỗn hợp khí

Hỗn hợp khí B : (2x + 28y)/(x+y) = 3,6 x 2 = 7,2

→ x = 4y → 80%  H 2  và 20% CO

a, 

Gọi a là mol O2, b là mol Cl2

=>                   (1) 

= 30,625.2= 61,25 

=> = 61,25

=>      (2) 

(1)(2) => a= 0,05; b= 0,15 

b, 

%VO2=0,05.100\0,2=25%

=> %VCl2=75%

\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)

\(\overline{M_x}=24.2=48\)

\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\)       48    = \(\dfrac{16}{16}=1\)

\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)

1. \(m_{hh}=0,3.64+0,3.32=28,8g\)

2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)

\(\Rightarrow\%V_{O_2}=50\%\)

3. \(m_{SO_2}=0,3.64=19,2g\)

\(m_{O_2}=0,3.32=9,6g\)

- Xét A:

Giả sử \(m_{SO_2}=m_{CH_4}=16\left(g\right)\)

\(n_{SO_2}=\dfrac{16}{64}=0,25\left(mol\right);n_{CH_4}=\dfrac{16}{16}=1\left(mol\right)\)

\(\overline{M}_A=\dfrac{16+16}{0,25+1}=25,6\left(g/mol\right)\)

- Xét B:

Do \(V_{Cl_2}=V_{O_2}\Rightarrow n_{Cl_2}=n_{O_2}\)

Giả sử \(n_{Cl_2}=n_{O_2}=1\left(mol\right)\)

\(\overline{M}_B=\dfrac{1.71+1.32}{1+1}=51,5\left(g/mol\right)\)

\(d_{A/B}=\dfrac{25,6}{51,5}\approx0,497\)

Đáp án A